Syn stereochemistry Study guides, Class notes & Summaries

Test Bank for Organic Chemistry 4e 4th Edition by David R. Klein. ISBN-13: 9594 Full chapters test bank PDF TABLE OF CONTENTS 1 A Review of General Chemistry: Electrons, Bonds, and Molecular Properties 1 1.1 Introduction to Organic Chemistry 2 1.2 The Structural Theory of Matter 3 1.3 Electrons, Bonds, and Lewis Structures 4 1.4 Identifying Formal Charges 7 1.5 Induction and Polar Covalent Bonds 8 1.6 Reading Bond-Line Structures 11 1.7 Atomic Orbitals 14 1.8 Valence Bond Theory 17 1.9 Molecular...

Basicity rules correct answers -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation correct answers -more stable equitorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection correct answers -gauche: substituent groups adjacent to eachother -grab middle and turn to put in plane Enantiomers correct answers -not superimposable mirror images -same besides stereochemistry Diast...

When naming carboxylic acids correct answers find the longest continuous carbon atom chain contianing the carboxylic acid group What is the prefix in carboxylic acids? correct answers -oate To name an ester, correct answers identify the alkyl group that is in the 'alcohol' portion of the molecule and name it; then identify the acid part of the molecule. The ester is named with the alkyl part first, and the acid part is named as a carboxylate. The terms ortho, meta, and para are used w...

IR Spectra correct answer: -Absorption of radiation causes vibrational excitation of functional groups *making it easy to ID functional groups* *0-5000cm-1* H NMR Spectra correct answer: *0-12ppm* C NMR Spectra correct answer: *0-200ppm* Mass Spec correct answer: -Used to measure the molecular weight (mass) of the compound. Alkyne Reactions correct answer: *1* Alkyne + H2/Pd &C = Alkene *2* Alkyne + H2/Lindlav Cat.= Cis Alkene *3* Alkyne + Li or Na/Liquid NH3= Trans Alkene ...

strong base, weak nucleophile correct answer: NaH strong base, weak nucleophile correct answer: DBN strong base, weak nucleophile correct answer: DBU strong base, strong nucleophile correct answer: HO- strong base, strong nucleophile correct answer: MeO- strong base, strong nucleophile correct answer: EtO- weak base, strong nucleophile correct answer: I- weak base, strong nucleophile correct answer: Br- weak base, strong nucleophile correct answer: Cl- weak ba...

Basicity rules correct answers -strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation correct answers -more stable equitorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxial Newman projection correct answers -gauche: substituent groups adjacent to eachother -grab middle and turn to put in plane Enantiomers correct answers -not superimposable mirror images -same besides stereochemistry Diast...

When naming carboxylic acids correct answers find the longest continuous carbon atom chain contianing the carboxylic acid group What is the prefix in carboxylic acids? correct answers -oate To name an ester, correct answers identify the alkyl group that is in the 'alcohol' portion of the molecule and name it; then identify the acid part of the molecule. The ester is named with the alkyl part first, and the acid part is named as a carboxylate. The terms ortho, meta, and para are used w...

What is the degree of substitution? <<ANSWERS>>>The number of alkyl groups a specific carbon is bonded to (more alkyl groups means more stable) What reagents are required in a dissolving metal reduction? <<ANSWERS>>>Na or Li, ammonia (NH3) as solvent Provide a summary of dissolving metal reduction <<ANSWERS>>>2 hydrogens (one equivalent) are added to an alkyne to form the E alkene (anti addition) What is the stereochemistry of the dissolving ...

Chapter 1-Structure and Bonding:Acids and Bases 1. How many total valence electrons are represented in the following electron configuration? 1s22s22px2 2py2 2pz1 or 1s22s22p5 a. 1 b. 3 c. 5 d. 7 e. 9 ANS: D Instructions: Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all nonbonding electrons. 2. Write: CH3CH2OH ethanol ANS: 3. The structure of urea is shown below. Fill in any nonbonding valence electrons that are missing from the l...

Test Bank for Organic Chemistry 4e 4th Edition by David R. Klein. ISBN-13: 9594 Full chapters test bank PDF TABLE OF CONTENTS 1 A Review of General Chemistry: Electrons, Bonds, and Molecular Properties 1 1.1 Introduction to Organic Chemistry 2 1.2 The Structural Theory of Matter 3 1.3 Electrons, Bonds, and Lewis Structures 4 1.4 Identifying Formal Charges 7 1.5 Induction and Polar Covalent Bonds 8 1.6 Reading Bond-Line Structures 11 1.7 Atomic Orbitals 14 1.8 Vale...